Product ID:GLDKS014 THYRONINE UPTAKE (TU E) TEST PACK, (SUPDAT)
MSDS Date:05/23/1990
FSC:6550
NIIN:00N041013
Kit Part:Y
MSDS Number: BSJGR

E I DU PONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637

Info Phone: 800-441-9250;800-435-7222

Cage: B0589

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

ALSO CONTAINS SODIUM AZIDE. SODIUM AZIDE WAS FOUND

RTECS: 9999999ZZ

AZIDE INJECTED AT LOW DOSES INTO CHICK EMBRYOS WAS

RTECS: 9999999ZZ

1,3-PROPANEDIOL, 2-AMINO-2-(HYDROXYMETHYL)-; (TRIS)

CAS: 77-86-1

RTECS: TY2900000

TRIS HYDROCHLORIDE

CAS: 1185-53-1

OCCURS W/IN 1 HR.INHAL OF 0.5 PPM HYDRAZOIC ACID

RTECS: 9999999ZZ

GAGGING. INHAL OF MIST/AEROSOL COULD PROVOKE RESP

RTECS: 9999999ZZ

SODIUM AZIDE IS ABSORB THRU

RTECS: 9999999ZZ

NOT SKIN HAZ AT <1%. SYMPS INCL CONT DERM/ECZEMA

RTECS: 9999999ZZ

SOME INDIVS MAY

RTECS: 9999999ZZ

OF TISS AROUND EYES) AS RSLT OF ALLERGIC RXN TO

RTECS: 9999999ZZ

INGESTING 50 ML OF 0.1% AZIDE CAN PRDCE

RTECS: 9999999ZZ

BLURRED VISION, ETC. CAN CAUSE PSYCHOTROPIC EFTS IN

RTECS: 9999999ZZ

ERUPTIONS, NAUS, VOMIT. LRG DOSES CAUSE MARKED

RTECS: 9999999ZZ

CAN CAUSE ALLERGIC RASH IN SENSIT INDIVS. RPTD

RTECS: 9999999ZZ

MUTAGENIC WHEN TESTED ON HAMSTER CELLS IN VITRO.

RTECS: 9999999ZZ

SODIUM SALT OF BARBITAL CAUSES BIRTH DEFECTS WHEN

RTECS: 9999999ZZ

BARBITURIC ACID, 5,5-DIETHYL-, SODIUM SALT; (SODIUM

CAS: 144-02-5

RTECS: CQ3850000

SODIUM AZIDE (SARA III)

CAS: 26628-22-8

RTECS: VY8050000

OSHA PEL 0.1 PPM (HN*3) S, C

ACGIH TLV: 0.11 PPM, C

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETAMIDE, 2-CHLORO-; (CHLOROACETAMIDE)

CAS: 79-07-2

RTECS: AB5075000

LD50 LC50 Mixture:LD50 (ORAL,RAT): 450 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: NO ADVERSE EFTS EXPECTED
UNDER NORMAL CNDTNS. HYDRAZOIC ACID VAPS: SICKENING ODOR; VERY
IRRIT. FOLLOWING EFTS FROM HYDRAZOIC ACIDS VAPS INCR W/INCR EXPOS:
HDCH, FALL IN BLOOD PRESS, WEAK , FAINTNESS, BLURRED VISION,
SHORTNESS OF BRTH, STUFFINESS, DIZZ/COLLAPSE; HEART PALPITATION.
RECOVERY USUALLY (ING 6)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:MAY LEAD TO ADDICTION.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH LOW BLOOD PRESSURE
MAY HAVE INCREASED SUSCEPTIBILITY TO TOXIC EFFECTS OF OVEREXPOSURE
TO THIS SUBSTANCE, BECAUSE IT CONTAINS SODIUM AZIDE.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. CALL PHYSICIAN. SKIN: FLUSH
WITH WATER AFTER CONTACT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE: IM MED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL
PHYSICIAN. INGESTION: IMMEDIATELY GIVE 2 GLASSES OF WATER & INDUCE
VOMIT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. CALL
PHYSICIAN.

Flash Point:NONFLAMMABLE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING MATERIAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . EVACUATE PERSONNEL TO SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE.
Unusual Fire/Explosion Hazard:HAZ GASES/VAPS PRDCED IN FIRE ARE CARBON
MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR,
HYDROGEN CHLORIDE. CONT W/ACIDS & ACIDIC SOLNS (SUPDAT)

Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY
PRECAUTIONS BEFORE PROCEEDING WITH CLEAN UP. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE REFRIGERATED (NOT A SAFETY
REQUIREMENT). DO NOT MIX WITH INCOMPATIBLES.
Other Precautions:AVOID CONTACT WITH EYES. AVOID CONTACT WITH SKIN.
AVOID CONTACT WITH CLOTHING. WASH THOROUGHLY AFTER HANDLING. AVOID
INHALATION OF DUST, VAPOR, MISTS OR AEROSOLS.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION SUFFICIENT TO KEEP AIRBORNE
CONCENTRATION BELOW CURRENT EXPOSURE LIMITS .
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APRV CHEMICAL WORKERS GOGGLES (FP N
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PART #/TRADE NAME: PART C, SODIUM BARBITOL REAGENT. BP: >212F,>100C @
760. MP: <32F,<0C @ 760. EXPLO HAZ: MAY CAUSE GENERATION OF VERY
IRRIT, HYDRAZOIC ACID GAS. MATLS TO AVOID: CHLORIDE + KOH) TO FOR M
EXPLO. INCOMPAT WITH ACIDS. LOWERING PH OF AZIDE SOLNS BELOW 6 MAY
GENERATE VERY IRRIT, FLAMMABLE HYDRAZOIC GAS.

Boiling Pt:B.P. Text:SUPP DATA
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Vapor Pres:18 @ 25C
Vapor Density:1
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:AQUEOUS
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
SODIUM AZIDE REACTS W/COPPER, LEAD, SILVER, MERCURY (ELEMENTAL), GOLD,
CARBON DISULFIDE, BR*2, HNO*3, (BENZOYL (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSES WITH HEAT.

Waste Disposal Methods:TU E PACK: DISPOSE PER FEDERAL, STATE AND LOCAL
GUIDELINES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.